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Highly selective sorption and luminescent sensing of small molecules demonstrated in a multifunctional lanthanide microporous metal-organic framework containing 1D honeycomb-type channels

Highly selective sorption and luminescent sensing of small molecules demonstrated in a multifunctional lanthanide microporous metal-organic framework containing 1D honeycomb-type channels

Chemistry 19(10): 3358-3365

A rare, robust microporous lanthanide metal-organic framework with 1D honeycomb-type channels is presented. Excellent adsorption capabilities for N(2), H(2), and CO(2) and significant selective sorption of CO(2) over N(2) and CH(4) were observed. Moreover, the guest-dependent luminescent behavior of these lanthanide materials shows a potential use for the sensing of small-molecule pollutants such as benzene and acetone.

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Accession: 053559155

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PMID: 23348797

DOI: 10.1002/chem.201203487

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