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Iron-catalyzed aerobic oxidation of allylic alcohols: the issue of C═C bond isomerization

Iron-catalyzed aerobic oxidation of allylic alcohols: the issue of C═C bond isomerization

Organic Letters 15(20): 5150-5153

An aerobic oxidation of allylic alcohols using Fe(NO3)3·9H2O/TEMPO/NaCl as catalysts under atmospheric pressure of oxygen at room temperature was developed. This eco-friendly and mild protocol provides a convenient pathway to the synthesis of stereodefined α,β-unsaturated enals or enones with the retention of the C-C double-bond configuration.

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Accession: 053985290

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PMID: 24099324

DOI: 10.1021/ol402434x

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