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Oxidative conversion of silyl enol ethers to α,β-unsaturated ketones employing oxoammonium salts

Oxidative conversion of silyl enol ethers to α,β-unsaturated ketones employing oxoammonium salts

Organic Letters 14(1): 154-157

The oxidative conversion of silyl enol ethers to α,β-unsaturated ketones using a less-hindered class of oxoammonium salts (AZADO(+)BF(4)(-)) is described. The reaction proceeds via the ene-like addition of oxoammonium salts to silyl enol ethers.

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Accession: 054825678

Download citation: RISBibTeXText

PMID: 22181054

DOI: 10.1021/ol2029417

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