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Proton-coupled electron shuttling in a covalently linked ruthenium-copper heterodinuclear complex



Proton-coupled electron shuttling in a covalently linked ruthenium-copper heterodinuclear complex



Journal of the American Chemical Society 133(46): 18570-3



A heterodinuclear complex based on a Ru(II)-TPA [TPA = tris(2-pyridylmethyl)amine] complex having a peripheral Cu(II)(bpy)(2) (bpy = 2,2'-bipyridine) group bonded through an amide linkage displayed reversible intramolecular electron transfer between the Ru and Cu complex units that can be controlled by protonation and deprotonation of the bridging amide moiety.

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Accession: 055260720

Download citation: RISBibTeXText

PMID: 22017339

DOI: 10.1021/ja208141b


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