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Reactivity of endo-3-bromocamphor with sulfur-centered nucleophiles by an electron transfer mechanism. Electrophilic behaviour of the 3-camphoryl radical

Reactivity of endo-3-bromocamphor with sulfur-centered nucleophiles by an electron transfer mechanism. Electrophilic behaviour of the 3-camphoryl radical

Organic and Biomolecular Chemistry 9(8): 2969-2974

The photostimulated reaction of arylthiolate ions with endo-3-bromocamphor produced both reduction and substitution products. The pK(a) and proton affinities of the conjugated acids were found to be good indicators of the reactivity.

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Accession: 055387759

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PMID: 21365113

DOI: 10.1039/c0ob01108h

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