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Regioselective electrosynthesis of rare 1,2,3,16-functionalized [60]fullerene derivatives

Angewandte Chemie 53(11): 3006-3010
Regioselective electrosynthesis of rare 1,2,3,16-functionalized [60]fullerene derivatives
Fullerene derivatives with different addition patterns exhibit different physical, chemical, and biological properties, which are important for fullerene applications. Novel and rare 1,2,3,16-functionalized [60]fullerene derivatives having a five-membered heterocycle fused to a [5,6]-junction were obtained with high regioselectivity by electrochemical derivatization of a [60]fulleroindoline. The product structures were determined by spectroscopic data and single-crystal X-ray analysis. The obtained high regioselectivity was rationalized using theoretical calculations.

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Accession: 055445631

PMID: 24500858

DOI: 10.1002/anie.201310565

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