EurekaMag.com logo
+ Site Statistics
References:
53,517,315
Abstracts:
29,339,501
+ Search Articles
+ Subscribe to Site Feeds
EurekaMag Most Shared ContentMost Shared
EurekaMag PDF Full Text ContentPDF Full Text
+ PDF Full Text
Request PDF Full TextRequest PDF Full Text
+ Follow Us
Follow on FacebookFollow on Facebook
Follow on TwitterFollow on Twitter
Follow on Google+Follow on Google+
Follow on LinkedInFollow on LinkedIn

+ Translate

Regioselective hydroformylation of sulfonamides using a scaffolding ligand



Regioselective hydroformylation of sulfonamides using a scaffolding ligand



Organic Letters 11(13): 2764-2767



A highly regioselective hydroformylation of allylic sulfonamides has been developed by employing a catalytic directing group. The reaction tolerates a wide range of electronically and sterically modified olefins, and only 10% of the scaffolding ligand is required to effectively control the regioselectivity.

(PDF same-day service: $19.90)

Accession: 055445678

Download citation: RISBibTeXText

PMID: 19489593

DOI: 10.1021/ol900921e



Related references

Application of a chiral scaffolding ligand in catalytic enantioselective hydroformylation. Journal of the American Chemical Society 132(42): 14757-9, 2011

A tetraphosphorus ligand for highly regioselective isomerization-hydroformylation of internal olefins. Journal of the American Chemical Society 128(50): 16058-16061, 2006

A novel triphosphoramidite ligand for highly regioselective linear hydroformylation of terminal and internal olefins. Organic Letters 15(5): 1048-1051, 2013

A model iridium hydroformylation system with the large bite angle ligand xantphos: reactivity with parahydrogen and implications for hydroformylation catalysis. Inorganic Chemistry 45(18): 7197-7209, 2006

Distal-selective hydroformylation using scaffolding catalysis. Journal of the American Chemical Society 136(24): 8556-8559, 2015

A new direction in enantioselective catalysis: scaffolding ligands in olefin hydroformylation. Angewandte Chemie 50(4): 809-812, 2011

Regioselective hydroformylation of allylic alcohols. Organic Letters 13(10): 2686-2689, 2011

Highly regioselective osmium-catalyzed hydroformylation. Chemical Communications 51(15): 3080-3082, 2015

Highly regioselective hydroformylation with hemispherical chelators. Chemistry 14(24): 7144-7155, 2008

An Effective Pd-Catalyzed Regioselective Hydroformylation of Olefins with Formic Acid. Journal of the American Chemical Society 138(45): 14864-14867, 2016

Regioselective hydroformylation of styrene and analogs catalyzed by 2r 5r 2 5 bisdiphenylphosphinomethylbicyclo 2.2.1 heptanerhodium i. Synlett (11): 711-712, 1990

A supramolecular catalyst for regioselective hydroformylation of unsaturated carboxylic acids. Angewandte Chemie 47(2): 311-315, 2007

Highly active, regioselective, and enantioselective hydroformylation with Rh catalysts ligated by Bis-3,4-diazaphospholanes. Journal of the American Chemical Society 127(14): 5040-5042, 2005

Completely regioselective hydroformylation of methyl n acetamidoacrylate by chiral rhodium phosphine catalysts. Tetrahedron Asymmetry 1(10): 693-696, 1990

Branched-regioselective hydroformylation with catalytic amounts of a reversibly bound directing group. Angewandte Chemie 47(38): 7346-7349, 2008