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Regioselective hydroformylation of sulfonamides using a scaffolding ligand

Organic Letters 11(13): 2764-2767
Regioselective hydroformylation of sulfonamides using a scaffolding ligand
A highly regioselective hydroformylation of allylic sulfonamides has been developed by employing a catalytic directing group. The reaction tolerates a wide range of electronically and sterically modified olefins, and only 10% of the scaffolding ligand is required to effectively control the regioselectivity.

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Accession: 055445678

PMID: 19489593

DOI: 10.1021/ol900921e

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