+ Site Statistics
+ Search Articles
+ PDF Full Text Service
How our service works
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ Translate
+ Recently Requested

Ring-opening metathesis polymerization of 18-e Cobalt(I)-containing norbornene and application as heterogeneous macromolecular catalyst in atom transfer radical polymerization



Ring-opening metathesis polymerization of 18-e Cobalt(I)-containing norbornene and application as heterogeneous macromolecular catalyst in atom transfer radical polymerization



Macromolecular Rapid Communications 35(21): 1840-1845



In the last decades, metallopolymers have received great attention due to their various applications in the fields of materials and chemistry. In this article, a neutral 18-electron exo-substituted η(4) -cyclopentadiene CpCo(I) unit-containing polymer is prepared in a controlled/"living" fashion by combining facile click chemistry and ring-opening meta-thesis polymerization (ROMP). This Co(I)-containing polymer is further used as a heterogeneous macromolecular catalyst for atom transfer radical polymerization (ATRP) of methyl methacrylate and styrene.

Please choose payment method:






(PDF emailed within 0-6 h: $19.90)

Accession: 055576674

Download citation: RISBibTeXText

PMID: 25250694

DOI: 10.1002/marc.201400365


Related references

Synthesis and application of a microgel-supported acylating reagent by coupled ring-opening metathesis polymerization and activators re-generated by electron transfer for atom transfer radical polymerization. Journal of Combinatorial Chemistry 12(2): 255-259, 2010

Synthesis of highly active ruthenium indenylidene complexes for atom-transfer radical polymerization and ring-opening-metathesis polymerization. Angewandte Chemie 42(25): 2876-2879, 2003

Facile synthesis of brush poly(phosphoamidate)s via one-pot tandem ring-opening metathesis polymerization and atom transfer radical polymerization. Macromolecular Rapid Communications 35(17): 1509-1515, 2014

A new class of ruthenium complexes containing Schiff base ligands as promising catalysts for atom transfer radical polymerization and ring opening metathesis polymerization. Journal of Molecular Catalysis A: Chemical 180(1-2): 67-76, 2002

Application of electrochemically generated molybdenum-based catalyst system to the ring-opening metathesis polymerization of norbornene and a comparison with the tungsten analogue. Applied Organometallic Chemistry 19(7): 834-840, 2005

Degradable copolymers with incorporated ester groups by radical ring-opening polymerization using atom transfer radical polymerization. Polimery 62(4): 262-271, 2017

Cascade synthesis of chiral block copolymers combining lipase catalyzed ring opening polymerization and atom transfer radical polymerization. Biomacromolecules 5(5): 1862-1868, 2004

One-Step Immobilization of Initiators for Surface Initiated Ring Opening Polymerization and Atom Transfer Radical Polymerization by Poly(norepinephrine) Coating. Journal of Nanoscience and Nanotechnology 15(2): 1597-1600, 2015

One-Step Immobilization of Initiators for Surface-Initiated Ring Opening Polymerization and Atom Transfer Radical Polymerization by Poly(norepinephrine) Coating. Journal of Nanoscience and Nanotechnology 15(2): 1597-1600, 2015

Synthesis and self-assembly of thermoresponsive PEG-b-PNIPAM-b-PCL ABC triblock copolymer through the combination of atom transfer radical polymerization, ring-opening polymerization, and click chemistry. Journal of Physical Chemistry. B 115(50): 14947-14955, 2011

Superior Cascade Ring-Opening/Ring-Closing Metathesis Polymerization and Multiple Olefin Metathesis Polymerization: Enhancing the Driving Force for Successful Polymerization of Challenging Monomers. Journal of the American Chemical Society 140(33): 10536-10545, 2018

Suspension ring-opening metathesis polymerization: the preparation of norbornene-based resins for application in organic synthesis. Journal of Organic Chemistry 69(10): 3319-3329, 2004

A catalyst for the simultaneous ring-opening metathesis polymerization/vinyl insertion polymerization. Angewandte Chemie 50(15): 3566-3571, 2011

Synthesis, characterization, and micellization of an epoxy-based amphiphilic diblock copolymer of e-caprolactone and glycidyl methacrylate by enzymatic ring-opening polymerization and atom transfer radical polymerization. Journal of polymer science Part A Polymer chemistry15 45(22): 5037-5049, 2007

Easily Accessible Ring Opening Metathesis and Atom Transfer Radical Polymerization Catalysts based on Arene, Norbornadiene and Cyclooctadiene Ruthenium Complexes Bearing Schiff Base Ligands. Advanced Synthesis & Catalysis 345(3): 393-401, 2003