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Synthesis, spectroscopic characterization and magnetic properties of homo- and heterodinuclear complexes of transition and non-transition metal ions with a new Schiff base ligand



Synthesis, spectroscopic characterization and magnetic properties of homo- and heterodinuclear complexes of transition and non-transition metal ions with a new Schiff base ligand



Spectrochimica Acta. Part A Molecular and Biomolecular Spectroscopy 71(4): 1555-1561



Four homodinuclear complexes of Ni(II)-Ni(II), Cu(II)-Cu(II), Co(II)-Co(II) and Co(III)-Co(II) and five heterodinuclear complexes of Co(III)-Zn(II), Co(III)-Cu(II), Co(III)-Ni(II), Cu(II)-Zn(II) and Zn(II)-Cu(II) with the octadentate Schiff base compartmental ligand 1,8-N-bis(3-carboxy)disalicylidene-3,6-diazaoctane-1,8-diamine (H4fsatrien) have been synthesized. The complexes have been characterized with the help of elemental analyses, molecular weights, molar conductances, magnetic susceptibilities and spectroscopic (UV-vis, IR, ESR) data. Cryomagnetic data also helped to elucidate the structural features of the Cu(II) complexes.

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Accession: 056086685

Download citation: RISBibTeXText

PMID: 18650125

DOI: 10.1016/j.saa.2008.06.002


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