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The structural determination of endohedral metallofullerene Gd@C(82) by XANES



The structural determination of endohedral metallofullerene Gd@C(82) by XANES



Chemical Communications 2008(4): 474-476



Although the Gd ion in Gd@C(82) has been shown to lie above the C-C bond on the C(2) axis as an anomalous structure from the MEM/Rietveld analysis, the present XANES study reveals that it lies above the hexagon on the C(2) axis as a normal structure, and Gd oscillates around its equilibrium position with an amplitude increasing with temperature increase.

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Accession: 056504405

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PMID: 18188472

DOI: 10.1039/b714603e


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