+ Site Statistics
References:
54,258,434
Abstracts:
29,560,870
PMIDs:
28,072,757
+ Search Articles
+ PDF Full Text Service
How our service works
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ Translate
+ Recently Requested

catena-Poly[[[bis-(N,N-dimethyl-formamide)iron(II)]-{μ-2,2'-bis-(diphenyl-phosphino-yl)-N,N'-[(1R,2R)-cyclo-hexane-1,2-di-yl]dibenzamide}] bis-(perchlorate) N,N-dimethyl-formamide disolvate



catena-Poly[[[bis-(N,N-dimethyl-formamide)iron(II)]-{μ-2,2'-bis-(diphenyl-phosphino-yl)-N,N'-[(1R,2R)-cyclo-hexane-1,2-di-yl]dibenzamide}] bis-(perchlorate) N,N-dimethyl-formamide disolvate



Acta Crystallographica. Section E, Structure Reports Online 65(Pt 12): M1512-3



The title extended solid coordination compound, {[Fe(C(44)H(40)N(2)O(4)P(2))(C(3)H(7)NO)(2)](ClO(4))(2)·2C(3)H(7)NO}(n), was crystallized un-ex-pectedly from the reaction mixture containing the Trost ligand (1R,2R)-(+)-1,2-diamino-cyclo-hexane-N,N'-bis-(2'-di-phenyl-phosphinobenzo-yl) and Fe(ClO(4))(2)·6H(2)O in a 1:1 ratio in dimethyl-formamide (DMF) under reflux conditions. The polymeric complex is characterized by Fe(II) metal centers that are coordinated by two oxidized Trost ligands, each coordinated in a bidentate fashion in a square plane, along with two DMF mol-ecules above and below the plane [average Fe-O(DMF) = 2.086 (4) Å], forming an overall pseudo-octa-hedral geometry. The Trost ligand binds adjacent Fe(II) centers, each Fe(II) being bound through the O atom of one of the phosphine oxides [average Fe-O(PPh2) = 2.115 (4) Å] and the carbonyl O atom of the adjacent amide [average Fe-O(amide) = 2.192 (3) Å]. Disorder is observed in the co-solvated solvent: there are two DMF mol-ecules per Fe(II) centre, which were modeled as one DMF mol-ecule with complete occupancy and the other being modeled in two positions with equal occupancy. Disorder was also observed with one of the perchlorate anions, which was modeled in two positions with 0.75:0.25 occupancy.

Please choose payment method:






(PDF emailed within 0-6 h: $19.90)

Accession: 056982886

Download citation: RISBibTeXText

PMID: 21578561

DOI: 10.1107/s1600536809045188


Related references

catena-Poly[[bis-(dimethyl-ammonium) [cadmate(II)-bis-(μ-1,1':4',1''-terphenyl-3,3''-dicarboxyl-ato)]] dimethyl-formamide disolvate. Acta Crystallographica. Section E, Structure Reports Online 67(Pt 1): M71, 2010

Poly[bis-(dimethyl-ammonium) [bis-(dimethyl-amine-κN)tris-(μ(2)-terephthalato-κO:O)dizinc(II)] N,N-dimethyl-formamide disolvate hexa-hydrate. Acta Crystallographica. Section E, Structure Reports Online 65(Pt 9): M1071-2, 2009

Di-μ(2)-methoxo-bis-{[μ-3,10,18,25-tetra-aza-penta-cyclo-[17.4.4.3.1.1]triconta-1(31),2,4(9),5,7,10,12,14,16(32),17,19(24),20,22,25,27,29-hexa-deca-ene-31,32-diolato]dizinc(II)} bis-(perchlorate) N,N-dimethyl-formamide disolvate. Acta Crystallographica. Section E, Structure Reports Online 67(Pt 3): M368, 2011

16-Isopropyl-5,9-dimethyl-tetra-cyclo-[10.2.2.0.0]hexa-dec-15-ene-5,13,14-tricarboxylic acid dimethyl-formamide disolvate. Acta Crystallographica. Section E, Structure Reports Online 66(Pt 6): O1318, 2010

(Dimethyl-formamide-κO)(2-hy-droxy-benzoato-κO,O)[tris-(1-methyl-1H-benzimidazol-2-ylmethyl-κN)amine-κN]manganese(II) perchlorate dimethyl-formamide monosolvate. Acta Crystallographica. Section E, Structure Reports Online 66(Pt 10): M1252, 2010

(Dimethyl-formamide)(2-methyl-propen-oato)[tris-(1-methyl-1H-benzimidazol-2-ylmeth-yl)amine]-manganese(II) perchlorate dimethyl-formamide solvate. Acta Crystallographica. Section E, Structure Reports Online 66(Pt 10): M1270, 2010

Poly[[bis-(dimethyl-formamide)[μ(7)-5,5'-(methyl-enedi-oxy)diisophthalato]dizinc] dimethyl-formamide monosolvate. Acta Crystallographica. Section E, Structure Reports Online 67(Pt 10): M1406, 2011

μ-Oxalato-bis-[(2,2'-bipyridyl)-copper(II)] bis(perchlorate) dimethyl-formamide disolvate monohydrate. Acta Crystallographica. Section E, Structure Reports Online 66(Pt 9): M1101-2, 2010

3,3'-Diphenyl-1,1'-[2,2'-oxybis(2,1-phenyl-ene)]diurea N,N-dimethyl-formamide disolvate. Acta Crystallographica. Section E, Structure Reports Online 64(Pt 1): O305-O306, 2007

Bis{μ-4'-[4-(quinolin-8-yloxymeth-yl)phen-yl]-2,2':6',2''-terpyridine}disilver(I) bis-(perchlorate) dimethyl-formamide disolvate. Acta Crystallographica. Section E, Structure Reports Online 65(Pt 12): M1674-5, 2009

catena-Poly[[[aqua-copper(II)]-bis-[μ-N,N'-bis-(pyridin-4-yl)isophthalamide]-[aqua-copper(II)]-di-μ-sulfato] dimethyl-formamide disolvate. Acta Crystallographica. Section E, Structure Reports Online 69(Pt 3): M150-M151, 2013

(Salicylato)[tris-(1-methyl-1H-benz-imidazol-2-ylmeth-yl)amine]copper(II) perchlorate dimethyl-formamide disolvate. Acta Crystallographica. Section E, Structure Reports Online 64(Pt 1): M19, 2007

catena-Poly[bis-(μ(4)-adipato-1:2:1':2'κO:O:O:O)bis-(N,N-dimethyl-formamide)-1κO,2κO-dicopper(II). Acta Crystallographica. Section E, Structure Reports Online 66(Pt 10): M1258, 2010

catena-Poly[[bis-(dimethyl-formamide-κO)cadmium(II)]-di-μ(2)-dicyanamido-κN:N. Acta Crystallographica. Section E, Structure Reports Online 65(Pt 12): M1550, 2009

catena-Poly[[bis-(N,N'-dimethyl-formamide)cadmium(II)]-μ(2)-oxalato. Acta Crystallographica. Section E, Structure Reports Online 64(Pt 1): M185, 2007