+ Site Statistics
+ Search Articles
+ PDF Full Text Service
How our service works
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ Translate
+ Recently Requested

Determination of semi-volatile organic compounds in the source of drinking water by gas chromatography triple quadruples mass spectrometry with auto solid phase extraction



Determination of semi-volatile organic compounds in the source of drinking water by gas chromatography triple quadruples mass spectrometry with auto solid phase extraction



Wei Sheng Yan Jiu 46(4): 645-657



To establish a method for detecting 21 semi-volatile organic compounds in the source of drinking water by gas chromatography triple quadruples mass spectrometry( GC-MS/MS). To process multiple samples at the same time, using large volume solid-phase extraction device for continuous injection. The water samples were extracted by C_(18) solid phase column, eluted with methylene chloride and ethylacetate, and then separated by DB-5MS capillary column. The target substance in the extractions was selected by gas chromatography triple quadruples spectrometry in selectedreaction monitoring( SRM) mode. Retention time and selected ions were used for qualitative analysis, acenaphthene-d_(10), phenanthrene-d_(10) and chrysene-d_(12) were used as internal standard for qualitative analysis of 21 semi-volatile organic compounds. The method was good sensitivity, stability and high selectivity, which could improve the sensitivity of target compounds by secondary mass spectrum scanning through reducing the background interference. The separate rates of 21 kinds of compounds were well, and the correlation coefficients were more than 0. 9902. The minimum detection concentration was 5. 0 × 10~(-5)mg/L, the average recovery rates were 72. 6%-127. 3% and the relativestandard deviation were 1. 05%-9. 89%. This method is simple, rapid with high accuracy and reliable, so it is suitable for detecting semi-volatile organic compounds in water.

Please choose payment method:






(PDF emailed within 1 workday: $29.90)

Accession: 057793396

Download citation: RISBibTeXText

PMID: 29903190


Related references

Determination of three volatile N-nitrosamine in drinking water by solid phase extraction and gas chromatography-triple quadrupole mass spectrometry with programmable temperature vaporizer-based large volume injection. Se Pu 37(2): 216-221, 2019

Determination of volatile organic compounds in water by headspace solid-phase microextraction gas chromatography coupled to tandem mass spectrometry with triple quadrupole analyzer. Analytica Chimica Acta 704(1-2): 87-97, 2011

Comprehensive analytical method for semi-volatile organic compounds in water samples by combination of disk-type solid-phase extraction and gas chromatography-mass spectrometry database system. Analytical Sciences 29(4): 483-486, 2013

Online in situ analysis of selected semi-volatile organic compounds in water by automated microscale solid-phase extraction with large-volume injection/gas chromatography/mass spectrometry. Journal of Chromatography. a 1176(1-2): 223-230, 2007

Simultaneous chemical and sensory characterization of volatile organic compounds and semi-volatile organic compounds emitted from swine manure using solid phase microextraction and multidimensional gas chromatography-mass spectrometry-olfactometry. Journal of Environmental Quality 37(2): 521-534, 2008

Fast analysis of volatile organic compounds and disinfection by-products in drinking water using solid-phase microextraction-gas chromatography/time-of-flight mass spectrometry. Journal of Chromatography. a 1201(2): 222-227, 2008

Determination of pesticide residues and related compounds in water and industrial effluent by solid-phase extraction and gas chromatography coupled to triple quadrupole mass spectrometry. Analytical and Bioanalytical Chemistry 405(24): 7697-7709, 2013

Determination of volatile organic compounds including alcohols in refill fluids and cartridges of electronic cigarettes by headspace solid-phase micro extraction and gas chromatography-mass spectrometry. Analytical and Bioanalytical Chemistry 409(5): 1247-1256, 2016

Optimization of microwave-assisted extraction followed by solid phase micro extraction and gas chromatography-mass spectrometry detection for the assay of some semi volatile organic pollutants in sebum. Journal of Chromatography. B, Analytical Technologies in the Biomedical and Life Sciences 825(1): 11-20, 2005

Determination of 61 organic pollutants in drinking water by solid phase extraction followed by liquid and gas chromatography coupled to tandem mass spectrometry an analytical strategy for a routine laboratory. International Journal of Environmental Analytical Chemistry 93(7): 1-20, 2012

Solid-phase microcolumn extraction and gas chromatography-mass spectrometry identification of volatile organic compounds emitted by paper. Talanta 80(1): 400-402, 2010

Determination of volatile organic compounds in drinking water by purge and trap gas chromatography/mass spectrometry. Wei Sheng Yan Jiu 35(4): 504-507, 2006

Air sampling with Empore solid phase extraction membranes and online single-channel desorption/liquid chromatography/mass spectrometry analysis: determination of volatile and semi-volatile organophosphate esters. Journal of Chromatography. a 1129(1): 1-8, 2006

The determination of volatile organic compounds in soils using solid phase microextraction with gas chromatography-mass spectrometry. HRC Journal of High Resolution Chromatography 19(9): 515-519, 1996

Comparison of LiquidLiquid Extraction, Simultaneous Distillation Extraction, Ultrasound-Assisted Solvent Extraction, and Headspace Solid-Phase Microextraction for the Determination of Volatile Compounds in Jujube Extract by Gas Chromatography/Mass Spectrometry. Analytical Letters 47(4): 654-674, 2014