+ Site Statistics
+ Search Articles
+ PDF Full Text Service
How our service works
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ Translate
+ Recently Requested

General Deposition of Metal-Organic Frameworks on Highly Adaptive Organic-Inorganic Hybrid Electrospun Fibrous Substrates

General Deposition of Metal-Organic Frameworks on Highly Adaptive Organic-Inorganic Hybrid Electrospun Fibrous Substrates

Acs Applied Materials and Interfaces 8(4): 2552-2561

Electrospun nanofibrous mats are ideal substrates for metal-organic frameworks (MOFs) crystal deposition because of their specific structural parameters and chemical tenability. In this work, we utilized organic-inorganic hybrid electrospun fibrous mats as support material to study the deposition of various MOF particles. HKUST-1 and MIL-53(Al) were produced through solvothermal method, while ZIF-8 and MIL-88B(Fe) were prepared using microwave-induced heating method. The synthesis procedure for both methods were simple and effective because the hybrid nanofibrous mats showed considerable affinity to MOF particles and could be used without additional modifications. The obtained MOF composites exhibited effective incorporation between MOF particles and the porous substrates. MIL-53(Al) composite was applied as fibrous sorbent and showed enhanced adsorption capacity and removal rate, as well as easier operation, compared with thepowdered sample. Moreover, MIL-53(Al) composite was easier to be regenerated compared with powder form.

Please choose payment method:

(PDF emailed within 0-6 h: $19.90)

Accession: 057924526

Download citation: RISBibTeXText

PMID: 26741023

DOI: 10.1021/acsami.5b10078

Related references

Series of inorganic-organic hybrid materials constructed from octamolybdates and metal-organic frameworks: syntheses, structures, and physical properties. Inorganic Chemistry 51(21): 11266-11278, 2012

Hybrid Metal-Organic-Framework/Inorganic Nanocatalyst toward Highly Efficient Discoloration of Organic Dyes in Aqueous Medium. Inorganic Chemistry 57(21): 13270-13278, 2018

Highly emissive Zn-Ln metal-organic frameworks with an unusual 3D inorganic subnetwork. Chemical Communications 48(64): 7964-7966, 2012

Polymer frameworks as templates for generating size-controlled metal nanoclusters: Active and reusable metal catalysts based on organic resins and on organic/inorganic composites. Journal of Molecular Catalysis A: Chemical 195(1-2): 219-223, 2003

Organic/inorganic hybrid nano-microstructured coatings on insulated substrates by electrospray deposition. Journal of Colloid and Interface Science 286(1): 414-416, 2005

Patterned deposition of metal-organic frameworks onto plastic, paper, and textile substrates by inkjet printing of a precursor solution. Advanced Materials 25(33): 4631-4635, 2013

Synergistic assembly of heavy metal clusters and luminescent organic bridging ligands in metal-organic frameworks for highly efficient X-ray scintillation. Journal of the American Chemical Society 136(17): 6171-6174, 2014

Ionothermal synthesis of zeolites, metal-organic frameworks, and inorganic-organic hybrids. Accounts of Chemical Research 40(10): 1005-1013, 2007

A highly-connected acentric organic-inorganic hybrid material with unique 3D inorganic and 3D organic connectivity. Chemical Communications 46(24): 4354-4356, 2010

Metal-Organic Frameworks: Tiny Pd@Co Core-Shell Nanoparticles Confined inside a Metal-Organic Framework for Highly Efficient Catalysis (Small 1/2015). Small 11(1): 70-70, 2015

Synthesis of highly porous inorganic adsorbents derived from metal-organic frameworks and their application in efficient elimination of mercury(II). Journal of Colloid and Interface Science 517: 61-71, 2018

Lanthanide organic-inorganic hybrids based on functionalized metal-organic frameworks (MOFs) for a near-UV white LED. Chemical Communications 50(97): 15443-6, 2014

Organic-inorganic hybrid zeolites containing organic frameworks. Science 300(5618): 470-472, 2003

Hybrid inorganic-organic adsorbents Part 1: Synthesis and characterization of mesoporous zirconium titanate frameworks containing coordinating organic functionalities. Acs Applied Materials and Interfaces 2(12): 3436-3446, 2010

Computational evaluation of metal pentazolate frameworks: inorganic analogues of azolate metal-organic frameworks. Chemical Science 9(13): 3367-3375, 2018