+ Site Statistics
+ Search Articles
+ PDF Full Text Service
How our service works
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ Translate
+ Recently Requested

High-throughput synthesis and characterization of nanocrystalline porphyrinic zirconium metal-organic frameworks



High-throughput synthesis and characterization of nanocrystalline porphyrinic zirconium metal-organic frameworks



Chemical Communications 52(50): 7854-7857



We describe and employ a high-throughput screening method to accelerate the synthesis and identification of pure-phase, nanocrystalline metal-organic frameworks (MOFs). We demonstrate the efficacy of this method through its application to a series of porphyrinic zirconium MOFs, resulting in the isolation of MOF-525, MOF-545, and PCN-223 on the nanoscale.

Please choose payment method:






(PDF emailed within 0-6 h: $19.90)

Accession: 057995768

Download citation: RISBibTeXText

PMID: 27247981

DOI: 10.1039/c6cc03264h


Related references

Topology-guided design and syntheses of highly stable mesoporous porphyrinic zirconium metal-organic frameworks with high surface area. Journal of the American Chemical Society 137(1): 413-419, 2015

Porous interpenetrated zirconium-organic frameworks (PIZOFs): a chemically versatile family of metal-organic frameworks. Chemistry 17(34): 9320-9325, 2011

Nanoporous metal oxides with tunable and nanocrystalline frameworks via conversion of metal-organic frameworks. Journal of the American Chemical Society 135(24): 8940-8946, 2013

Synthesis, structure, and metalation of two new highly porous zirconium metal-organic frameworks. Inorganic Chemistry 51(12): 6443-6445, 2012

Pore-Environment Engineering with Multiple Metal Sites in Rare-Earth Porphyrinic Metal-Organic Frameworks. Angewandte Chemie 57(18): 5095-5099, 2018

Modulation by Amino Acids: Toward Superior Control in the Synthesis of Zirconium Metal-Organic Frameworks. Chemistry 22(38): 13582-7, 2016

Microwave-assisted solvothermal synthesis of zirconium oxide based metal-organic frameworks. Chemical Communications 49(35): 3706-3708, 2013

A highly stable porphyrinic zirconium metal-organic framework with shp-a topology. Journal of the American Chemical Society 136(51): 17714-7, 2014

Hybrid inorganic-organic adsorbents Part 1: Synthesis and characterization of mesoporous zirconium titanate frameworks containing coordinating organic functionalities. Acs Applied Materials and Interfaces 2(12): 3436-3446, 2010

Functional porphyrinic metal-organic frameworks: crystal engineering and applications. Dalton Transactions 41(14): 3879-3888, 2012

Systematic Engineering of Single Substitution in Zirconium Metal-Organic Frameworks toward High-Performance Catalysis. Journal of the American Chemical Society 139(51): 18590-18597, 2017

High-throughput screening of metal-organic frameworks for CO2 separation. Acs Combinatorial Science 14(4): 263-267, 2012

High-throughput computational screening of metal-organic frameworks. Chemical Society Reviews 43(16): 5735-5749, 2014

Green and rapid synthesis of zirconium metal-organic frameworks via mechanochemistry: UiO-66 analog nanocrystals obtained in one hundred seconds. Chemical Communications 53(43): 5818-5821, 2017

Zirconium Metal-Organic Frameworks Assembled from Pd and Pt P N N N P Pincer Complexes: Synthesis, Postsynthetic Modification, and Lewis Acid Catalysis. Inorganic Chemistry 57(5): 2663-2672, 2018