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Pincer-Nickel-Catalyzed Allyl-Aryl Coupling between Allyl Methyl Ethers and Arylzinc Chlorides



Pincer-Nickel-Catalyzed Allyl-Aryl Coupling between Allyl Methyl Ethers and Arylzinc Chlorides



Journal of Organic Chemistry 80(24): 12627-12634



The P,N,N-pincer nickel complex [Ni(Cl){N(2-Ph2PC6H4)(2'-Me2NC6H4)}]-catalyzed allyl-aryl coupling was studied. The reaction of allyl methyl ethers, including (1-methoxyallyl)arenes and (3-methoxyprop-1-en-1-yl)arenes, with arylzinc chlorides afforded linear (E)-alkenes in high yields, whereas the reaction of (E)-1-methoxytridec-2-ene with p-Me2NC6H4ZnCl generated a mixture of linear and branched alkenes.

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Accession: 058558287

Download citation: RISBibTeXText

PMID: 26556232

DOI: 10.1021/acs.joc.5b02151


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