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A supramolecular assembly based on an engineered hemoprotein exhibiting a thermal stimulus-driven conversion to a new distinct supramolecular structure

Oohora, K.; Onuma, Y.; Tanaka, Y.; Onoda, A.; Hayashi, T.

Chemical Communications 53(51): 6879-6882

2017

ISSN/ISBN: 1364-548X
PMID: 28604909
DOI: 10.1039/c7cc02678a
Accession: 059419672
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Supramolecular assembly of an engineered hemoprotein with an externally-attached heme moiety via an azobenzene or stilbene linker demonstrates drastic structural transitions between two distinct forms: the thermodynamically stable fiber-type assembly and the kinetically trapped metastable micelle-type assembly induced by transient thermal stimulus.

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