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Crystal structure of ( E )- N 1 -[(anthracen-9-yl)methyl-idene]- N 4 -phenyl-benzene-1,4-di-amine



Crystal structure of ( E )- N 1 -[(anthracen-9-yl)methyl-idene]- N 4 -phenyl-benzene-1,4-di-amine



Acta Crystallographica. Section E Crystallographic Communications 73(Pt 2): 137-140



The title compound, C27H20N2, a Schiff base synthesized via a condensation reaction between anthracene-9-carbaldehyde and N-phenyl-p-phenyl-enedi-amine, crystallizes with three independent mol-ecules in the asymmetric unit. The three mol-ecules have slightly varying overall conformations, all having trans conformations with respect to the C=N bond. In the crystal, the packing features N-H⋯N hydrogen bonds, which connect mol-ecules into chains extending along the c-axis direction, inter-linked by C-H⋯π inter-actions (minimum H⋯Cg = 2.65 Å) into sheets lying parallel to (001).

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Accession: 059567399

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PMID: 28217328


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