Gas-phase elimination kinetics of 1-substituted ethyl acetates. Effect of polar substituents at the α carbon of secondary acetates
José A. Hernández A.; Gabriel Chuchani
International Journal of Chemical Kinetics 15(3): 205-218
1983
ISSN/ISBN: 0538-8066 DOI: 10.1002/kin.550150302
Accession: 061719539
PDF emailed within 0-6 h: $19.90
Related References
Gabriel Chuchani; Ignacio Martin; Irama Avila 1979: Effect of substituents in the gas-phase elimination kinetics of β-substituted ethyl acetates International Journal of Chemical Kinetics 11(6): 561-567Martin, I.; Chuchani, G.; Avila, I.; Rotinov, A.; Olmos, R. 1980: Gas-phase pyrolysis kinetics of 2-substituted-2-propyl acetates. Effect of substituents on the .alpha.-carbon of tertiary acetates The Journal of Physical Chemistry 84(1): 9-11
Reikonnen, N.; Martin, I.; Chuchani, G.; Lubinkowski, J. 1985: The electronic effects of substituents at the acyl carbon in the gas-phase elimination kinetics of tert -butyl -substituted acetates International Journal of Chemical Kinetics 17(3): 337-343
Alexandra Rotinov; Gabriel Chuchani 1984: Linear correlation of polar substituents in the gas-phase pyrolyses of ethyl α-substituted acetates International Journal of Chemical Kinetics 16(10): 1267-1273
Gabriel Chuchani; Jaime Alvarez G; Ignacio Martín 1991: Correlation of alkyl and polar substituents in the elimination kinetics of 2-substituted ethyl methanesulphonates in the gas phase Journal of Physical Organic Chemistry 4(7): 399-403
Gabriel Chuchani; Ignacio Martin; German Fraile; Omar Lingstuyl; Maria, J. Diaz 1978: Kinetics of the gas-phase elimination of isopropyl α-substituted acetates International Journal of Chemical Kinetics 10(8): 893-897
Tosta, M.M.; Mora, J.R.; Cordova, T.; Chuchani, G. 2010: Quantum chemical calculations of the homogeneous, unimolecular, gas-phase elimination kinetics of primary alkyl acetates and (dimethylamino)alkyl acetates: Neighboring group participation in 4-(dimethylamino)-1-butyl acetate Journal of Molecular Structure: THEOCHEM 952(1-3): 46-55
Rama Sastry, B.V.; Chiou, C.Y. 1970: Some aspects of the blockade of neuro muscular transmission by iodo acetates bromo acetates chloro acetates and fluoro acetates and their choline esters in the rat phrenic nerve diaphragm preparation Toxicology and Applied Pharmacology 17(1): 303
Martin, I.; Chuchani, G. 1981: Steric acceleration in the pyrolysis kinetics of 2-substituted ethyl acetates The Journal of Physical Chemistry 85(25): 3902-3904
Gonzalez, N.; Martin, I.; Chuchani, G. 1985: Correlation of alkyl and polar substituents at the alcoholic side of tertiary acetates with the rate of pyrolyses in the gas phase Journal of Physical Chemistry (1952) 89(7): 1314-1318
Robert, J.F.; Panouse, J.J. 1982: Derivatives of imidazo 2 1 b thiazole 5. allylic transposition during the synthesis of ethyl 2 imino 3 alkyl thiazolin 4 yl acetates and ethyl 5 6 dihydroimidazo 2 1 b thiazol 3 yl acetates Journal of Heterocyclic Chemistry 19(2): 343-348
Herize, A.; Dominguez, R.M.; Rotinov, A.; Nunez, O.; Chuchani, G. 1999: Gas-phase elimination kinetics of ethyl, isopropyl and tert -butyl N, N -diethylcarbamates. application of tafttopsom correlation for substituents other than carbon at the acid side of organic ethyl esters Journal of Physical Organic Chemistry 12(3): 201-206
Gabriel Chuchani; Ignacio Martin; Alexandra Rotinov; Rosa, M. Dominguez; David, G. Morris; Alistair, G. Shepherd 1988: The effect of ring size on the gas phase elimination kinetics of cycloalkyl acetates International Journal of Chemical Kinetics 20(2): 145-151
Gabriel Chuchani; Jose, A. Hernandez; Magdalia Yepez; Miguel, E. Alonso 1977: Kinetics of the gas-phase elimination of isopropyl α-halo acetates and the taft correlation International Journal of Chemical Kinetics 9(5): 811-818
Luo, B.; Guan, H.; Hu, C. 1997: Tandem Reaction of Ethyl α-(Per(poly)fluoroalkyl)acetates with Allylic Alcohols: a Convenient Synthesis of Ethyl α-(2-Alkenyl)-α-(per(poly)- fluoroacyl)acetates The Journal of Organic Chemistry 62(12): 4174-4175
Picquet-Varrault, B´ne´dicte; Doussin, J-François; Durand-Jolibois, R´gine; Carlier, P 2001: FTIR spectroscopic study of the OH-induced oxidation of two linear acetates: ethyl and n-propyl acetates Physical Chemistry Chemical Physics, PCCP 3(13): 2595-2606
Chuchani, G.; Triana, J.L.; Rotinov, A.; Caraballo, D.F. 1981: Gas-phase elimination kinetics of ethyl esters of chloroacetate, 3-chloropropionate, and 4-chlorobutyrate. the electronic effects of substituents at the acyl carbon The Journal of Physical Chemistry 85(9): 1243-1245
Carolina Arcila; Maria Pino; Jacek Lubinkowski; Jose Adan Hernandez A; Gabriel Chuchani 1984: Steric influence in the direction of elimination of gas-phase pyrolyses of several highly branched secondary acetates International Journal of Chemical Kinetics 16(1): 57-67
Chuchani, G.; Rotinov, A.; Dominguez, R.M.; Gonzalez, N. 1984: Gas-phase elimination kinetics of (dimethylamino)alkyl acetates. the ion-pair mechanism through neighboring group participation The Journal of Organic Chemistry 49(22): 4157-4160
Chuchani, G.; Rotinov, A.; Dominguez, R.M.; Gonzalez, N. 1984: Gas-phase elimination kinetics of (dimethylamino)alkyl acetates. The ion-pair mechanism throught neighboring group participation Journal of Organic Chemistry 49(22): 4157-4160