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Thermodynamics and mechanism of partitioning of pyridylalkanamides in n-octanol/ water and di-n-butyl ether/water



Thermodynamics and mechanism of partitioning of pyridylalkanamides in n-octanol/ water and di-n-butyl ether/water



International Journal of Pharmaceutics 38(1): 47-57



The partition coefficient of 12 isomeric and homologous pyridylalkanamides was measured at 4 temperatures in n-octanol/water and di-n-butyl ether/water. The thermodynamic results were analyzed for enthalpy-entropy compensation effects by plots of.DELTA.G vs.DELTA.H and by isokinetic relationships.

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Accession: 061957411

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DOI: 10.1016/0378-5173(87)90096-2


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