+ Site Statistics
+ Search Articles
+ PDF Full Text Service
How our service works
Request PDF Full Text
+ Follow Us
Follow on Facebook
Follow on Twitter
Follow on LinkedIn
+ Subscribe to Site Feeds
Most Shared
PDF Full Text
+ Translate
+ Recently Requested

Nickel-catalyzed cross-coupling of β-carbonyl alkenyl pivalates with arylzinc chlorides

Nickel-catalyzed cross-coupling of β-carbonyl alkenyl pivalates with arylzinc chlorides

Organic and Biomolecular Chemistry 16(6): 1029-1036

The nickel-catalyzed cross-coupling reaction of β-carbonyl alkenyl pivalates with arylzinc reagents generates 3-aryl-substituted α,β-unsaturated carbonyl compounds via C-O bond cleavage. The reaction features mild reaction conditions, a wide scope of substrates, and good functional group tolerance.

Please choose payment method:

(PDF emailed within 0-6 h: $19.90)

Accession: 065353905

Download citation: RISBibTeXText

PMID: 29354846

DOI: 10.1039/c7ob02947k

Related references

Cross-coupling of aryl/alkenyl pivalates with organozinc reagents through nickel-catalyzed C-O bond activation under mild reaction conditions. Angewandte Chemie 47(52): 10124-7, 2009

Efficient cross-coupling of aryl chlorides with arylzinc reagents catalyzed by amido pincer complexes of nickel. Organic Letters 9(21): 4335-4338, 2007

Nickel-Catalyzed β,γ-Dicarbofunctionalization of Alkenyl Carbonyl Compounds via Conjunctive Cross-Coupling. Journal of the American Chemical Society 139(31): 10657-10660, 2017

Palladium-catalyzed cross-coupling of 6-bromo-2-methylbenzothiazole with arylzinc chlorides. Russian Chemical Bulletin 42(11): 1925-1926, 1993

Cobalt-Catalyzed Cross-Couplings between Alkenyl Acetates and Aryl or Alkenyl Zinc Pivalates. Angewandte Chemie 57(35): 11436-11440, 2018

Pincer-Nickel-Catalyzed Allyl-Aryl Coupling between Allyl Methyl Ethers and Arylzinc Chlorides. Journal of Organic Chemistry 80(24): 12627-12634, 2015

Nickel complexes supported by quinoline-based ligands: synthesis, characterization and catalysis in the cross-coupling of arylzinc reagents and aryl chlorides or aryltrimethylammonium salts. Dalton Transactions 41(34): 10453-10464, 2012

Cross-coupling of aryltrimethylammonium iodides with arylzinc reagents catalyzed by amido pincer nickel complexes. Journal of Organic Chemistry 77(7): 3658-3663, 2012

Nickel-Catalyzed Reductive Cross-Coupling of Benzyl Chlorides with Aryl Chlorides/Fluorides: A One-Pot Synthesis of Diarylmethanes. Organic Letters 18(12): 2860-2863, 2016

Stereospecific, Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of Allylic Pivalates To Deliver Quaternary Stereocenters. Organic Letters 19(16): 4355-4358, 2017

Efficient cross-coupling of functionalized arylzinc halides catalyzed by a nickel chloride-diethyl phosphite system. Organic Letters 7(22): 4871-4874, 2005

Synthesis of Functionalized Diaryl Sulfides by Cobalt-Catalyzed Coupling between Arylzinc Pivalates and Diaryl Disulfides. Organic Letters 2018, 2018

Nickel-catalyzed decarboxylative C-P cross-coupling of alkenyl acids with P(O)H compounds. Journal of Organic Chemistry 79(17): 8118-8127, 2015

Nickel-catalyzed cross-coupling reaction of aryl fluorides and chlorides with grignard reagents under nickel/magnesium bimetallic cooperation. Journal of the American Chemical Society 127(51): 17978-9, 2005

Nickel-catalyzed C-P cross-coupling of diphenylphosphine oxide with aryl chlorides. Organic and Biomolecular Chemistry 10(48): 9627-9633, 2013