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Binding for endohedral-metallofullerene superatoms induced by magnetic coupling

Binding for endohedral-metallofullerene superatoms induced by magnetic coupling

Chemical Communications 54(95): 13383-13386

To design new materials based on artificial superatoms, clarifying their involved interaction is particularly important. In this study, we discuss first-principle calculations to show that the interaction between endohedral metallofullerenes (EMFs) of U@C28 can lead to different chemical and physical adsorption structures. Especially, these structures are derived from different magnetic coupling resonances, and they can transform by changing the distance between U@C28 superatoms. These findings will promote the future development for bottom-up assembling of new functional materials and even devices.

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Accession: 065711900

Download citation: RISBibTeXText

PMID: 30421751

DOI: 10.1039/c8cc08200f

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