Hashish.1 Synthesis of (+/-) -delta1-and delta 6-3,4-cis-cannabidiols and their isomerization by acid catalysis

Handrick, G.R.; Razdan, R.K.; Uliss, D.B.; Dalzell, H.C.; Boger, E.

Journal of Organic Chemistry 42(15): 2563-2568

1977


ISSN/ISBN: 0022-3263
PMID: 17656
DOI: 10.1021/jo00435a007
Accession: 068518069

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Abstract
The total synthesis of (.+-.)-.DELTA.1- and .DELTA.6-3,4-cis-cannabidiols (CBD) ) transformation products of cis-CBD were isolated and identified as the ring closed cis-cannabinoids. The rate of the reaction and the relative proportions of products were dependent on the acid concentration.