5,6-Dihydro-1,3-oxazines. XXIII. Chemistry of 2-chloromethyloxazines. Formation of phosphoranes and phosphonates. use of .alpha.,.beta. unsaturated oxazines as a common intermediate for the synthesis of aldehydes, ketones, and acids
Malone, G.R.; Meyers, A.I.
The Journal of Organic Chemistry 39(5): 623-628
1974
ISSN/ISBN: 0022-3263 DOI: 10.1021/jo00919a009
Accession: 080912242
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References
Meyers, A.I.; Kovelesky, A.C.; Jurjevich, A.F. 1973: Chemistry of dihydro-1,3-oxazines. XXI. 1,4-Addition of organometallics to 2-alkenyldihydro-1,3-oxazines. Synthesis of .alpha.-substituted aldehydes and ketones The Journal of Organic Chemistry 38(12): 2136-2143Meyers, A.I.; Smith, E.M.; Ao, M.S. 1973: Chemistry of dihydro-1,3-oxazines. XX. Synthesis of .alpha.-branched ketones from dihydro-1,3-oxazines via the ketenimine intermediate. .alpha.-Substituted ketones from a stable ketenimine The Journal of Organic Chemistry 38(12): 2129-2136
Malone, G.R.; Meyers, A.I. 1974: Chemistry of 1,6-dihydro-1,3-oxazines. XXII. Chemistry of 2-chloromethyl-5,6-dihydro-1,3-oxazines. Grignard coupling and metalation studies. Synthesis of .alpha.-chloroaldehydes and arylacetic acids The Journal of Organic Chemistry 39(5): 618-623
Meyers, A.I.; Nabeya, A.; Adickes, H.W.; Fitzpatrick, J.M.; Malone, G.R.; Politzer, I.R. 1969: Aldehydes from dihydro-1,3-oxazines. II. Synthesis of .alpha.,.beta.-unsaturated aldehydes and their C-1 deuterated derivatives Journal of the American Chemical Society 91(3): 764-765
Narwid, T.A.; Meyers, A.I. 1974: Chemistry of dihydro-1,3-oxazines. 24. Formation of pyrroles from dihydro-1,3-oxazines The Journal of Organic Chemistry 39(17): 2572-2574
Meyers, A.I.; Smith, E.M.; Jurjevich, A.F. 1971: Dihydro-1,3-oxazines. XIII. Synthesis of specifically alkylated unsymmetrical ketones. Method for assembling ketones with .alpha.-(quaternary carbons) Journal of the American Chemical Society 93(9): 2314-2316
Eliseev, O.; Ivashkin, P.; Ostapenko, A.; Lesiv, A.; Khomutova, Y.; Ioffe, S.; Lapidus, A. 2006: Catalytic Carbonylation of 3-Bromomethyl-5,6-dihydro-4 H -1,2-oxazines: General Approach to the Synthesis of 3-Methoxycarbonylmethyl-5,6-dihydro-4 H -1,2-oxazines from Available Precursors Synlett 2006(14): 2239-2240
Xu, D.; Lin, Y.; Chen, Y.; Zhang, J.; Cao, W.; Chen, J.; Wong, M.S. 2013: Synthesis and characterization of oxadisilole-fused-3,4-dihydro-2H-naphtho[2,1-e]-1,3-oxazines and 3,4-dihydro-2H-anthra[2,1-e]-1,3-oxazines Tetrahedron 69(30): 6144-6149
Meyers, A.I.; Narwid, T.A.; Collington, E.W. 1971: Dihydro-1,3-oxazines. XIV . a versatile synthesis of pyrrolo[2,1-c] [1,3,4H] oxazines and a new approach to pyrroles Journal of Heterocyclic Chemistry 8(5): 875-876
Andrey, A.T.; Alexey, V.L.; Yulia, A.K.; Yulia, V.N.; Sema, L.I. 2009: Rearrangement of 3-alkylidene-2-siloxy-tetrahydro-1,2-oxazines ASENA A new approach toward the synthesis of 3--hydroxyalkyl-5,6-dihydro-4H-1,2-oxazines Tetrahedron 65(23): 4578-4592
Calow, A.D.J.; Batsanov, A.S.; Fernández, E.; Solé, C.; Whiting, A. 2012: Novel transformation of α,β-unsaturated aldehydes and ketones into γ-amino alcohols or 1,3-oxazines via a 4 or 5 step, one-pot sequence Chemical Communications 48(93): 11401-11403
Meyers, A.I.; Nabeya, A.; Adickes, H.W.; Politzer, I.R.; Malone, G.R.; Kovelesky, A.C.; Nolen, R.L.; Portnoy, R.C. 1973: Synthesis of aldehydes from dihydro-1,3-oxazines The Journal of Organic Chemistry 38(1): 36-56
Meyers, A.I.; Nabeya, A.; Adickes, H.W.; Politzer, I.R. 1969: Aldehydes from dihydro-1,3-oxazines. I. Synthesis of aliphatic aldehydes and their C-1 deuterated derivatives Journal of the American Chemical Society 91(3): 763-764
Meyers, A.; Malone, G.; Adickes, H. 1970: Syntheses dihydro-1,3-oxazines. XI. a synthesis of functionally substituted aldehydes Tetrahedron Letters 11(42): 3715-3718
Meyers, A.; Kovelesky, A. 1969: Syntheses with dihydro-1,3-oxazines. IX. a simple synthesis of α-phenylaldehydes and ketones Tetrahedron Letters 10(54): 4809-4812
Meyers, A.I.; Kovelesky, A.C. 1969: Syntheses via dihydro-1,3-oxazines. VII. a simple synthesis of unsymmetrical ketones Journal of the American Chemical Society 91(21): 5887-5888
Shatzmiller, S.; Lidor, R.; Shalom, E. 1986: Regiocontrolled Synthesis of 4-Halo-5,6-Dihydro-4H-1,2-Oxazines; a Novel Route for α-Fluorovinyl Ketones Israel Journal of Chemistry 27(1): 33-38
Meyers, A.I.; Smith, E.M. 1972: Synthesis of ketones from dihydro-1,3-oxazines via stepwise alkyl or aryl introduction The Journal of Organic Chemistry 37(26): 4289-4293
Hasegawa, M.; Suga, T.; Soeta, T.; Ukaji, Y. 2020: Synthesis of 3,6-Dihydro-2H-1,2-oxazines via Dimethylsulfoxonium Methylide Addition to α,β-Unsaturated Nitrones Journal of Organic Chemistry 85(17): 11258-11264
Yoon, S.C.; Kim, K.; Park, Y.J. 2001: Hetero-Diels-Alder reactions of alpha-aryl-beta-monohalo-alpha-nitrosoethylenes: diastereoselective synthesis of 6-substituted 3-aryl-4-halo-5,6-dihydro-4H-1,2-oxazines Journal of Organic Chemistry 66(22): 7334-7341