Etard reactions. I. Nature of complexes and their reactions with some oxygen and nitrogen donor molecules

Makhija, R.C.; Stairs, R.A.; Makhija, R.C; Stairs, R.A

doi:10.1139/v68-211

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Etard reactions. I. Nature of complexes and their reactions with some oxygen and nitrogen donor molecules

Makhija, R.C.; Stairs, R.A.

Canadian Journal of Chemistry 46(8): 1255-1260

1968

ISSN/ISBN: 0008-4042

DOI: 10.1139/v68-211
Accession: 083752501

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Summary

Dilute carbon tetrachloride solutions of chromyl chloride and toluene react to form a product of empirical composition, C 6 H 5 CH 3• 2CrO 2 Cl 2 (1). On refluxing 1 with carbon tetrachloride solutions of pyridine, α-picoline, acetonitrile, dioxan, tetrahydrofuran, and triethylamine, adducts of approximate compositions C 6 H 5 CH 3• 2CrO 2 Cl 2• 2D (D = donor molecule) are obtained.Results of magnetic susceptibility, infrared, and preliminary X-ray observations are discussed. Possible structures for 1 and for the ternary adducts are described.